Adelaide Research & Scholarship
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https://hdl.handle.net/2440/106799
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| Type: | Journal article |
| Title: | Biosynthetically-inspired oxidations of capillobenzopyranol |
| Author: | Pepper, H. Lam, H. George, J. |
| Citation: | Organic and Biomolecular Chemistry, 2017; 15(22):4811-4815 |
| Publisher: | Royal Society of Chemistry |
| Issue Date: | 2017 |
| ISSN: | 1477-0520 1477-0539 |
| Statement of Responsibility: | Henry P. Pepper, Hiu C. Lam and Jonathan H. George |
| Abstract: | The synthesis of verrubenzospirolactone from its proposed biosynthetic precursor, capillobenzopyranol, has been shown to be chemically feasible via a simple reaction sequence. The key steps are a chemoselective furan oxidation mediated by NaClO₂, a stereoselective dehydration of a γ-methoxybutenolide, and an intramolecular Diels-Alder reaction. |
| Rights: | This journal is © The Royal Society of Chemistry 2017 |
| DOI: | 10.1039/c7ob00868f |
| Grant ID: | http://purl.org/au-research/grants/arc/DP160103393 |
| Published version: | http://dx.doi.org/10.1039/c7ob00868f |
| Appears in Collections: | Aurora harvest 8 Chemistry publications |
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