Adelaide Research & Scholarship
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https://hdl.handle.net/2440/113786
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Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Liu, J.-W. | - |
| dc.contributor.author | Su, H.-F. | - |
| dc.contributor.author | Wang, Z. | - |
| dc.contributor.author | Li, Y.-A. | - |
| dc.contributor.author | Zhao, Q.-Q. | - |
| dc.contributor.author | Wang, X.-P. | - |
| dc.contributor.author | Tung, C.-H. | - |
| dc.contributor.author | Sun, D. | - |
| dc.contributor.author | Zheng, L.-S. | - |
| dc.date.issued | 2018 | - |
| dc.identifier.citation | Chemical Communications, 2018; 54(35):4461-4464 | - |
| dc.identifier.issn | 1359-7345 | - |
| dc.identifier.issn | 1364-548X | - |
| dc.identifier.uri | http://hdl.handle.net/2440/113786 | - |
| dc.description.abstract | A 90-nucleus silver cluster (SD/Ag38) cocapped by tBuC6H4S‾ and PhCOO‾ ligands was synthesized using hetero-anion template method. Single-crystal X-ray diffraction (SCXRD) revealed a 90-nucleus metallic dumbbell-like core constructed by two large W5O19@Ag38 heads sandwiching one slender (SO4)2@Ag14 waist. Both W5O19⁸‾ and SO4²‾ templates were in situ generated and synergistically induced the formation of the largest known anion-templated silver cluster. Although SD/Ag38 is emission-silent at room temperature, increasingly brighter near-infrared (NIR) emission at ca. 742 nm was detected on cooling from 293 to 93 K. | - |
| dc.description.statementofresponsibility | Jia-Wei Liu, Hai-Feng Su, Zhi Wang, Yan-An Li, Quan-Qin Zhao, Xing-Po Wang, Chen-Ho Tung, Di Sun and Lan-Sun Zheng | - |
| dc.language.iso | en | - |
| dc.publisher | Royal Society of Chemistry | - |
| dc.rights | This journal is©The Royal Society of Chemistry 2018 | - |
| dc.source.uri | http://dx.doi.org/10.1039/c8cc01767k | - |
| dc.title | A giant 90-nucleus silver cluster templated by hetero-anions | - |
| dc.type | Journal article | - |
| dc.identifier.doi | 10.1039/c8cc01767k | - |
| pubs.publication-status | Published | - |
| Appears in Collections: | Aurora harvest 3 Chemistry publications | |
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