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https://hdl.handle.net/2440/17790
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DC Field | Value | Language |
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dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Kramarczuk, K. | - |
dc.contributor.author | Zaitseva, N. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.date.issued | 2005 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 2005; 690(6):1549-1555 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.issn | 1872-8561 | - |
dc.identifier.uri | http://hdl.handle.net/2440/17790 | - |
dc.description | Copyright © 2005 Elsevier B.V. All rights reserved. | - |
dc.description.abstract | The Pd(0)/Cu(I)-catalysed reactions between Co3(μ3-CBr) (CO)9 and W(Ctriple bond; length of mdashCCtriple bond; length of mdashCH)(CO)3Cp gives the C5 complex {Cp(OC)3W}Ctriple bond; length of mdashCCtriple bond; length of mdashCC{Co3(CO)9} (2). Similarly, Co3(μ3-CBr)(μ-dppm)(CO)7 and W(Ctriple bond; length of mdashCCtriple bond; length of mdashCH)(CO)3Cp or Ru(Ctriple bond; length of mdashCCtriple bond; length of mdashCH)(dppe)Cp* give {Cp(OC)3W}Ctriple bond; length of mdashCCtriple bond; length of mdashCC{Co3(μ-dppm)(CO)7} and {Cp*(dppe)Ru}Ctriple bond; length of mdashCCtriple bond; length of mdashCC{Co3(μ-dppmn)(CO)7} (5). An attempt to prepare a C3 analogue from Ru(Ctriple bond; length of mdashCH)(PPh3)2Cp and Co3(μ3-CBr)(CO)9 gave instead the acyl derivative {Cp(Ph3P)2Ru}Ctriple bond; length of mdashCC(O)C{Co3(CO)8(PPh3)} (7). The X-ray structures of 2, 5 and 7 are reported: the C5 chains in 2 and 5 have an essentially unperturbed –Ctriple bond; length of mdashC–Ctriple bond; length of mdashC–Ctriple bond; length of mdash formulation. | - |
dc.description.statementofresponsibility | Michael I. Bruce, Kathy A. Kramarczuk, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White | - |
dc.description.uri | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description | - |
dc.language.iso | en | - |
dc.publisher | Elsevier Science Sa | - |
dc.source.uri | http://dx.doi.org/10.1016/j.jorganchem.2004.12.019 | - |
dc.title | Some complexes containing carbon chains end-capped with tungsten or ruthenium groups and tricobalt carbonyl clusters | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1016/j.jorganchem.2004.12.019 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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