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https://hdl.handle.net/2440/17822
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Type: | Journal article |
Title: | The syntheses and structures of some main group complexes of the sterically hindered N,N'-bis(2,6-diisopropylphenyl)-4-toluamidinate ligand |
Author: | Boere, Rene T. Cole, Marcus Lawford Junk, Peter C. |
Citation: | New Journal of Chemistry, 2005; 29(1):128-134 |
Publisher: | Royal Society Chemistry |
Issue Date: | 2005 |
ISSN: | 1144-0546 |
School/Discipline: | School of Chemistry and Physics : Chemistry |
Statement of Responsibility: | René T. Boeré, Marcus L. Cole and Peter C. Junk |
Abstract: | The stoichiometric reaction of the bulky benzamidine N,N’-bis(2,6-diisopropylphenyl)-4-toluamidine (HDippAm) with the metal alkyls BunLi (1 : 1 in THF), Bu₂Mg (2 : 1 in THF) and Me₂Al (1 : 1 in Et₂O) is presented. This provides the mononuclear dihapto benzamidinate compounds [Li(DippAm)(THF)2] (1), [Mg(DippAm)₂] (2) and [Al(DippAm)Me₂] (3), respectively. Compound 3 was also obtained by salt elimination using dimethylaluminium chloride and 1. All three compounds exhibit sterically strained geometries that are maintained in solution at increased temperatures. Compound 3 displays exceptional thermal and aerobic stability, while 2 constitutes a rare example of non-porphyrin supported square planar magnesium. |
Rights: | © Royal Society of Chemistry 2005 |
DOI: | 10.1039/b409086a |
Published version: | http://www.rsc.org/publishing/journals/NJ/article.asp?doi=b409086a |
Appears in Collections: | Chemistry publications |
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