Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/17903
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dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Smith, M. | - |
dc.contributor.author | Zaitseva, N. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.date.issued | 2003 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 2003; 670(1-2):170-177 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/2440/17903 | - |
dc.description | Copyright © 2003 Elsevier Science B.V. | - |
dc.description.abstract | Reactions of Co3(μ3-CBr)(μ-dppm)(CO)7 with {Au[P(tol)3]}2{μ-(C6-point triple bond; length half of m-dashC)n} (n=2–4) have given {Co3(μ-dppm)(CO)7}{μ3:μ3-C(C6-point triple bond; length half of m-dashC)nC} [n=2 (1), 3 (2), 4 (3)] containing carbon chains capped by the cobalt clusters. Tetracyanoethene reacts with 2 to give {Co3(μ-dppm)(CO)7}2{μ3:μ3-C(C6-point triple bond; length half of m-dashC)2C[=C(CN)2]C[=C(CN)2]C} (4). X-ray structural characterisation of 1, 3 and 4 are reported, that for 3 being the first of a cluster-capped C10 chain. | - |
dc.description.statementofresponsibility | Michael I. Bruce, Mark E. Smith, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White | - |
dc.description.uri | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description | - |
dc.language.iso | en | - |
dc.publisher | Elsevier Science Sa | - |
dc.source.uri | http://dx.doi.org/10.1016/s0022-328x(02)02186-1 | - |
dc.subject | Carbon chains | - |
dc.subject | Cobalt clusters | - |
dc.subject | Capped clusters | - |
dc.subject | C10 chains | - |
dc.title | A new approach to the synthesis of carbon chains capped by metal clusters | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1016/S0022-328X(02)02186-1 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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