Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/23530
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Single and double nucleophilic attack on cluster-bonded allenylidenes: Synthesis of phosphorus heterocycles |
Author: | Bruce, M. Kramarczuk, K. Skelton, B. White, A. Zaitseva, N. |
Citation: | Inorganica Chimica Acta, 2006; 359(3):938-945 |
Publisher: | Elsevier Science SA |
Issue Date: | 2006 |
ISSN: | 0020-1693 |
Statement of Responsibility: | Michael I. Bruce, Kathy A. Kramarczuk, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
Abstract: | Further studies of the attack of bidentate tertiary phosphines, such as dppm and dppe, and the related diarsine dpam, on Ru3(μ-H){μ3-C2CHR(OH)}(CO)9 (R = H, Me) are described, together with the X-ray determined structures of [Ru3(μ3-C2CH2PPh2CH2CH2PPh2)(CO)9]BF4 (6) and Ru3(μ-H){μ3-C2CHMePPh2CHdouble bond; length as m-dashPPh2}(CO)9 (7) (containing diphospha heterocycles), Ru3(μ-H){μ3-CH2(OH)C2PPh2CH2PPh2}(CO)8 (8) (containing a phosphonium-alkynyl ligand also coordinated to a cluster Ru atom) and Ru3(μ-H)(μ3-CCdouble bond; length as m-dashCHAsPh2CH2AsPh2)(CO)9 (9) (containing an arsino-allenylidene ligand). These complexes are formed by nucleophilic attack of the Group 15 ligand on an alkynyl or allenylidene ligand on the cluster. |
Keywords: | alkynyl allenylidene cluster complex phosphorus heterocycles ruthenium |
DOI: | 10.1016/j.ica.2005.06.049 |
Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504086/description#description |
Published version: | http://dx.doi.org/10.1016/j.ica.2005.06.049 |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.