Adelaide Research & Scholarship
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https://hdl.handle.net/2440/34869
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| Type: | Journal article |
| Title: | Reversible Sm(III)/Sm(II) redox chemistry of an organosamarium(III) complex |
| Author: | Wang, Jun Amos, Ruth I. J. Frey, Alistair S. P. Gardiner, Michael G. Cole, Marcus Lawford Junk, Peter C. |
| Citation: | Organometallics, 2005; 24 (10):2259-2261 |
| Publisher: | American Chemical Society |
| Issue Date: | 2005 |
| ISSN: | 0276-7333 |
| School/Discipline: | School of Chemistry and Physics |
| Statement of Responsibility: | Jun Wang, Ruth I. J. Amos, Alistair S. P. Frey, and Michael G. Gardiner, Marcus L. Cole and Peter C. Junk |
| Abstract: | A binuclear samarium(III) complex featuring the -1:1-bound dianion of 1,4-di-tert-butyl-1,4-diazabuta-1,3-diene has been prepared which exhibits reversible redox behavior, reverting to the samarium(II) precursor when dissolved in tetrahydrofuran. The new samarium(III) complex has been characterized by 1H and 13C NMR spectral data, microanalytical data, magnetic moment measurements in solution, and an X-ray crystal structure determination. |
| Description: | Copyright © 2005 American Chemical Society |
| DOI: | 10.1021/om050172a |
| Published version: | http://pubs.acs.org/cgi-bin/abstract.cgi/orgnd7/2005/24/i10/abs/om050172a.html |
| Appears in Collections: | Chemistry publications |
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