Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4357
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Type: Journal article
Title: Two tetracobalt cluster complexes: Preparation and molecular structures of Co₄(μ-dppm)₂(μ-CO)₃(CO)₅ and CO₄(μ-CO)₃(CO)₆(η-C₆H₆)
Other Titles: Two tetracobalt cluster complexes: Preparation and molecular structures of Co(4)(mu-dppm)(2)(mu-CO)(3)(CO)(5) and CO(4)(mu-CO)(3)(CO)(6)(eta-C(6)H(6))
Author: Bruce, M.
Carty, A.
Ellis, B.
Low, P.
Skelton, B.
White, A.
Udachin, K.
Zaitseva, N.
Citation: Australian Journal of Chemistry: an international journal for chemical science, 2001; 54(4):277-281
Publisher: C S I R O Publishing
Issue Date: 2001
ISSN: 0004-9425
1445-0038
Statement of
Responsibility: 
Michael I. Bruce, Arthur J. Carty, Benjamin G. Ellis, Paul J. Low, Brian W. Skelton, Allan H. White, Konstantin A. Udachin and Natasha N. Zaitseva
Abstract: The crystal and molecular structures of the title complexes (1) and (2) are described. Each contains a Co4 tetrahedron, one face of which is edge-bridged by three μ-CO ligands. In (1), a pair of mutually orthogonal Co-Co bonds are bridged by the two dppm (dppm = bis(diphenylphosphino)methane) ligands. The structure of the benzene complex was determined at 153 and 300 K; as with other arene-Co4 clusters, the η6-benzene ligand sits on the apical (i.e. non-CO-bridged) Co atom.
Rights: © CSIRO 2001
DOI: 10.1071/CH01077
Published version: http://www.publish.csiro.au/index.cfm?paper=CH01077
Appears in Collections:Aurora harvest 2
Chemistry publications

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