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|Title:||Crystal and molecular structures of Ru3(CO)12-n(PMe3)n(n = 1,2)|
|Citation:||Australian Journal of Chemistry, 1997; 50(2):163-168|
|Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva|
|Abstract:||The crystal and molecular structures of the title compounds are described. Both contain a triangular Ru3 core [average Ru-Ru 2·853 (n = 1), 2·837 Å (n = 2)], with the PMe3 ligands occupying equatorial positions. For n = 2, substantial twisting about the Ru-Ru bonds results in one CO group adopting a semibridging position across the Ru-Ru vector joining a substituted Ru with the Ru(CO)4 fragment. Comparisons are also made with the previously determined n = 3 complex|
|Description:||© CSIRO 1997|
|Appears in Collections:||Chemistry publications|
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