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https://hdl.handle.net/2440/43789
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Type: | Journal article |
Title: | Preparation, structure and some chemistry of FcC≡CC≡CC≡CRu(dppe)Cp |
Other Titles: | Preparation, structure and some chemistry of FcCtriple barCCtriple barCCtriple barCRu(dppe)Cp |
Author: | Bruce, M. Humphrey, P. Jevric, M. Skelton, B. White, A. |
Citation: | Journal of Organometallic Chemistry, 2007; 692(12):2564-2574 |
Publisher: | Elsevier Science Sa |
Issue Date: | 2007 |
ISSN: | 0022-328X 1872-8561 |
Statement of Responsibility: | Michael I. Bruce, Paul A. Humphrey, Martyn Jevric, Brian W. Skelton and Allan H. White |
Abstract: | The synthesis of Fc(C{triple bond, long}C)3Ru(dppe)Cp (2) from Fc(C{triple bond, long}C)3SiMe3 and RuCl(dppe)Cp is described, together with its reactions with tcne to give the tetracyano-dienyl FcC{triple bond, long}CC{triple bond, long}C{C[{double bond, long}C(CN)2]}2Ru(dppe)Cp (3) and -cyclobutenyl FcC{triple bond, long}CC{triple bond, long}C{C{double bond, long}CC(CN)2C(CN)2}Ru(dppe)Cp (4), with Co2(μ-dppm)n(CO)8-2n (n = 0, 1) to give FcC2{Co2(CO)6}C2{Co2(CO)6}C{triple bond, long}CRu(dppe)Cp (5) and FcC{triple bond, long}CC{triple bond, long}CC2{Co2(μ-dppm)(CO)4}Ru(dppe)Cp (6), respectively, and with Os3(CO)10(NCMe)2 to give Os3{μ3-C2C{triple bond, long}CC{triple bond, long}C[Ru(dppe)Cp]}(CO)10 (7). On standing in solution, the latter isomerises to the cyclo-metallated derivative Os3(μ-H){μ3-C[Ru(dppe)Cp]CCC[(η-C5H3)FeCp]}(CO)8 (8). X-ray structural determinations of 1, 2, 6 and 7 are reported. © 2007 Elsevier B.V. All rights reserved. |
Description: | Copyright © 2007 Elsevier B.V. All rights reserved. |
DOI: | 10.1016/j.jorganchem.2007.02.043 |
Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description |
Published version: | http://dx.doi.org/10.1016/j.jorganchem.2007.02.043 |
Appears in Collections: | Aurora harvest Chemistry publications |
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