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https://hdl.handle.net/2440/4384
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Type: | Journal article |
Title: | Pentakis-methoxycarbonylcyclopentadiene chemistry. Some ruthenium, osmium and rhenium complexes |
Author: | Bruce, M. Humphrey, P. Williams, M. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1997; 50(12):1113-1117 |
Publisher: | CSIRO Publishing |
Issue Date: | 1997 |
ISSN: | 0004-9425 |
Abstract: | <jats:p> The reaction between Ru(O2CMe)2(PPh3)2 and HC5(CO2Me)5 affrded orange Ru(O2CMe)-{ C5(CO2Me)5}(PPh3)2, which on standing in methanolic solution in air lost PPh3 and was converted into purple {Ru(µO2CMe)[C5(CO2Me)5](PPh3)}2O. The C5(CO2Me)5 ligands chelate the ruthenium atoms via two ester carbonyl oxygens. The reaction of RuCl(O2CMe)(CO)(PPh3)2 with Tl[C5(CO2Me)5] in MeCN gave cream [Ru(O2CMe)(CO)(NCMe)(PPh3)2] [C5(CO2Me)5]. The syntheses of [C5(CO2Me)5]¯ salts of the [Ru(C=CHPh)(PPh3)2Cp]+, [Ru3H(CO)12]+, [Os(NCMe)(PPh3)2Cp]+, [OsH2(PPh3)2Cp]+ and [Re(CO)3(NCMe)3]+ cations are also reported.</jats:p> |
DOI: | 10.1071/C97169 |
Published version: | http://dx.doi.org/10.1071/c97169 |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
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