Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4388
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| Type: | Journal article |
| Title: | Some chemistry of Ru3(m-H)(m3-CMeCHCMe)(CO)9: reactions with diphenylethyne and characterization of a digold derivative |
| Author: | Bruce, M. Gulbis, J. Humphrey, P. Surynt, R. Tiekink, E. |
| Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1997; 50(9):875-878 |
| Publisher: | CSIRO Publishing |
| Issue Date: | 1997 |
| ISSN: | 0004-9425 |
| Statement of Responsibility: | Michael I. Bruce, Jacqueline M. Gulbis, Paul A. Humphrey, Richard J. Surynt and Edward R. T. Tiekink |
| Abstract: | <jats:p> The complex Ru3(µ3-CEtCMeCPhCPh)(CO)7{Au2(PPh3)2} (3) has been shown by a single-crystal X-ray structure determination to contain a C4Au2Ru3 cluster with an unusual geometry, consisting of the Au2 unit interacting with a C4Ru3 pentagonal bipyramid. Complex (3) was obtained from [O{Au(PPh3)}3] [BF4]/[ppn] [Co(CO)4] and the product (2) obtained from C2Ph2 and Ru3(µ-H)-(µ3-CMeCHCMe)(CO)9, previously assumed to have a CMeCEtCPhCPh ligand.</jats:p> |
| DOI: | 10.1071/C97089 |
| Published version: | http://dx.doi.org/10.1071/c97089 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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