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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4482
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dc.contributor.authorBruce, M.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.contributor.authorZaitseva, N.-
dc.date.issued1999-
dc.identifier.citationInorganic Chemistry Communications, 1999; 2(1):17-20-
dc.identifier.issn1387-7003-
dc.identifier.urihttp://hdl.handle.net/2440/4482-
dc.description.abstractThermolysis of Ru3(μ3-C=C=CPh2)(μ-dppm)(μ-CO)(CO)7 affords sequentially Ru3(μ3-PPhCH2PPh3)(μ3-C9H5Ph2)(CO)n (n = 6 (3), 5 (4)) by trapping of the Ph group (from P---C bond cleavage in the dppm ligand) by the allenylidene and cyclisation to a 1,3-diarylindenyl ligand, which is attached to the cluster in 3 via one of the Ar groups and in 4 by the η2:η2:η5-indenyl group; similar experiments with the di-4-tolylallenylidene provide information concerning the course of these reactions.-
dc.description.statementofresponsibilityMichael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva-
dc.description.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/600912/description#description-
dc.language.isoen-
dc.publisherElsevier BV-
dc.source.urihttp://dx.doi.org/10.1016/s1387-7003(98)00135-x-
dc.subjectCrystal structures-
dc.subjectPhenyl migration-
dc.subjectRuthenium complexes-
dc.subjectAllenylidene complexes-
dc.subjectCarbonyl cluster complexes-
dc.titleMigration of phenyl from dppm to allenylidene and cyclisation to 1,3-diarylindenyl on an Ru3 cluster-
dc.typeJournal article-
dc.identifier.doi10.1016/S1387-7003(98)00135-X-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
Appears in Collections:Aurora harvest 6
Chemistry publications

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