Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4483
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| Type: | Journal article |
| Title: | An unusual intramolecular metallalactone formation from coordinated alkoxide and CO: molecular structure of Au3Ru3{m3-h1:h1:h1,h2-CCHCPh-2OC(O)}(CO)8(PPh3)3 |
| Author: | Bruce, M. Skelton, B. White, A. Zaitseva, N. |
| Citation: | Inorganic Chemistry Communications, 1999; 2(10):453-455 |
| Publisher: | Elsevier BV |
| Issue Date: | 1999 |
| ISSN: | 1387-7003 |
| Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
| Abstract: | Sequential treatment of Ru3(μ-H){μ3-C2CPh2(OH)}(CO)9 with K[BHBus3] and AuCl(PPh3) afforded Au3Ru3{μ3-η1:η1:η1,η2-CCHCPh2OC(O)}(CO)8(PPh3)3, formed by intramolecular attack of alkoxide on an adjacent CO ligand, and characterised by a single-crystal X-ray study. |
| Keywords: | Metallalactone Gold Ruthenium Cluster Crystal structures |
| Description: | Copyright © 1999 Elsevier Science S.A. |
| DOI: | 10.1016/S1387-7003(99)00117-3 |
| Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/600912/description#description |
| Published version: | http://dx.doi.org/10.1016/s1387-7003(99)00117-3 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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