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Type: Journal article
Title: An unusual intramolecular metallalactone formation from coordinated alkoxide and CO: molecular structure of Au3Ru3{m3-h1:h1:h1,h2-CCHCPh-2OC(O)}(CO)8(PPh3)3
Author: Bruce, M.
Skelton, B.
White, A.
Zaitseva, N.
Citation: Inorganic Chemistry Communications, 1999; 2(10):453-455
Publisher: Elsevier BV
Issue Date: 1999
ISSN: 1387-7003
Statement of
Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva
Abstract: Sequential treatment of Ru3(μ-H){μ3-C2CPh2(OH)}(CO)9 with K[BHBus3] and AuCl(PPh3) afforded Au3Ru3{μ3-η1:η1:η1,η2-CCHCPh2OC(O)}(CO)8(PPh3)3, formed by intramolecular attack of alkoxide on an adjacent CO ligand, and characterised by a single-crystal X-ray study.
Keywords: Metallalactone
Crystal structures
Description: Copyright © 1999 Elsevier Science S.A.
DOI: 10.1016/S1387-7003(99)00117-3
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Appears in Collections:Aurora harvest 2
Chemistry publications

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