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Type: Journal article
Title: Unusual reactions of ruthenium-polycyanocarbon complexes: formation of an h²-CNR ligand and cleavage of C(sp²)-CN bonds
Other Titles: Unusual reactions of ruthenium-polycyanocarbon complexes: formation of an h(2)-CNR ligand and cleavage of C(sp(2))-CN bonds
Author: Bruce, M.
Skelton, B.
White, A.
Zaitseva, N.
Citation: Inorganic Chemistry Communications, 2001; 4(11):617-620
Publisher: Elsevier Science BV
Issue Date: 2001
ISSN: 1387-7003
Statement of
Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva
Abstract: Unusual formation of an η2-bonded polycyanocarbon ligand from tetracyanoethene, C2(CN)4 (tcne) and the allylic ligand in Ru{η3-CHPhCHC=CPh(C6-point triple bond; length half of m-dashCPh)}(PPh3)Cp* (1), and migration of CN from the polycyanocarbon in Ru{C[=C(CN)2]CPh=C(CN)2}(dppm)Cp* (3), have been established by crystal structure determinations on Ru{C(CH=CHPh)=CPhC[CPh=C(CN)2]C(CN)(η2-CN)}(PPh3)Cp* (2) and Ru(CN){C(CN)C[CPh=C(CN)2]PPh2CH2PPh2}Cp* (4), which are the respective products.
Keywords: Ruthenium
Crystal structure
CN group migration
DOI: 10.1016/S1387-7003(01)00280-5
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