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https://hdl.handle.net/2440/4485
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Type: | Journal article |
Title: | Rearrangements of 1,3-diynes on ruthenium cluster carbonyls: isolation and structure of Ru6(PhCHC3C6H4)2(CO)15 |
Author: | Bruce, M. Skelton, B. White, A. Zaitseva, N. |
Citation: | Inorganic Chemistry Communications, 1998; 1(4):134-136 |
Publisher: | Elsevier BV |
Issue Date: | 1998 |
ISSN: | 1387-7003 |
Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
Abstract: | Thermolysis of Ru3(μ3-PhC2C6-point triple bond; length half of m-dashCPh)(μ-CO)(CO)9 results in dimerisation, with concomitant internal cyclisation of the 1,3-diyne ligands to two methyleneindyne molecules which are attached in η2 and η4 modes to a novel Ru6 cluster core. |
Keywords: | Crystal structures Ruthenium complexes 1,3-Diyne complexes Cluster complexes |
DOI: | 10.1016/S1387-7003(98)00035-5 |
Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/600912/description#description |
Published version: | http://dx.doi.org/10.1016/s1387-7003(98)00035-5 |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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