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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4604
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dc.contributor.authorBruce, M.-
dc.contributor.authorZaitseva, N.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.date.issued1996-
dc.identifier.citationJournal of Organometallic Chemistry, 1996; 515(1-2):143-154-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/2440/4604-
dc.descriptionCopyright © 1996 Published by Elsevier Science B.V.-
dc.description.abstractHeating RU3(μ-dppm)(CO)9(PPh3) (2) for 90 min in refluxing toluene resulted inthe formation of Ru4(μ4-PPh)(μ4-PPh2C6H4CO)(μ-PPh2CH2)(CO)8 (3) and Ru3{μ3-PPh(C6H4)}(μ-PPh2CH2)(μ-PPh2)(μ-CO)(CO)6 (4) as the major products (41%); other complexes identified were Ru3{μ3-PPhCH2PPh(C6H4)}(CO)9 (5) and Ru2(μ-PPhC6H4PPhCH2)(CO)6−n(PPh3)n[n = 1(6), 0(7)]. The transformations involve oxidative addition of aromatic C---H and P---C bonds to the cluster, elimination of benzene and carbonylation of the aryl-Ru bond, as well as cluster disproportionation. X-ray structures of 3, 4 and 6 are presented.-
dc.description.statementofresponsibilityMichael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White-
dc.language.isoen-
dc.publisherElsevier BV-
dc.source.urihttp://dx.doi.org/10.1016/0022-328x(95)06051-w-
dc.subjectClusters-
dc.subjectCarbonyl-
dc.subjectCrystal structure-
dc.subjectPyrolysis-
dc.subjectRuthenium-
dc.titlePyrolysis of Ru3(m-dppm)(CO)9(PPh3): formation of novel Ru4 and Ru3 clusters-
dc.typeJournal article-
dc.identifier.doi10.1016/0022-328X(95)06051-W-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
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Chemistry publications

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