Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4608
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| Type: | Journal article |
| Title: | Some neutral ruthenium complexes and a novel 1,3-elimination reaction reaction: Preparation of some chiral ruthenium acetylides |
| Author: | Bruce, M. Hall, B. Zaitseva, N. Skelton, B. White, A. |
| Citation: | Journal of Organometallic Chemistry, 1996; 522(2):307-310 |
| Publisher: | Elsevier BV |
| Issue Date: | 1996 |
| ISSN: | 0022-328X |
| Statement of Responsibility: | Michael I. Bruce, Ben C. Hall, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White |
| Abstract: | Reactions of RuCl(PPh3)2Cp* with 1-alkynes in non-polar solvents afford the neutral vinylidene complexes RuCl(C=CHR)(PPh3) Cp* [R=Ph (X-ray structure), Bu1, SiMe3, CO2Me]; a novel 1,3 elimination of HCl induced by NaOMe in the presence of a variety of ligands gives the chiral-at-metal complexes Ru(Ctriple bond; length as m-dashCR)(L)(PPh3)Cp* [L=CO, C2H4 (X-ray structure), PR3, P(OR)3, O2, S2, CS2 (for example)]. |
| Keywords: | Crystal structure Chirality Ruthenium Vinylidene |
| Rights: | Copyright © 1996 Published by Elsevier Science B.V. |
| DOI: | 10.1016/0022-328X(96)06200-6 |
| Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description |
| Published version: | http://dx.doi.org/10.1016/0022-328x(96)06200-6 |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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