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https://hdl.handle.net/2440/4719
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Type: | Journal article |
Title: | Do carbanions undergo 1,2 hydrogen transfers in the gas phase? |
Author: | Dua, S. Adams, G. Sheldon, J. Bowie, J. |
Citation: | Journal of the Chemical Society, Perkin Transactions 2, 1996; 1(6):1251-1256 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 1996 |
ISSN: | 1472-779X 1364-5471 |
Abstract: | Certain anions X–⁻CH–CH₂–Y and X–CH₂⁻CH–Y interconvert under collisional activation conditions in the gas phase. Experiments designed to probe the mechanism(s) of particular interconversions suggest (i) that the ions MeO–CH₂–⁻CH–CN and MeO–⁻CH–CH₂–CN interconvert via 1,2 H transfer processes, and (ii) when X = Ph and Y = CO₂Me or CN, deuterium labelling and fragmentation data indicate that equilibration of Ph–⁻CHCH₂Y and PhCH₂–⁻CHY occurs, at least in part, by proton transfer to and from the phenyl ring. |
DOI: | 10.1039/P29960001251 |
Published version: | http://dx.doi.org/10.1039/p29960001251 |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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