Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4862
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| Type: | Journal article |
| Title: | Unusual coupling of diynes and CO on an Ru3 cluster: crystal structure of Ru3{m3-CPhCC(O)C(SiMe3)C(C CSiMe3)CCPh}(m-dppm)(m-CO)(CO)6 |
| Author: | Bruce, M. Zaitseva, N. Skelton, B. White, A. |
| Citation: | Russian Chemical Bulletin, 1998; 47(5):983-987 |
| Publisher: | Springer Science and Business Media LLC |
| Issue Date: | 1998 |
| ISSN: | 1066-5285 1573-9171 |
| Statement of Responsibility: | ruthenium; carbonyl clusters; alkyne complexes - diynes; silylalkynes - coupling of diynes and carbon monoxide |
| Abstract: | Among several products isolated in the reaction between Ru3(μ3-PhC2C≡CPh)(μ-dppm)(CO)8 and Me3SiCэCCэCSiMe3 was the Ru3{μ3-CPhCC(O)C(SiMe3)C(C≡CSiMe3)CCPh)(μ-ddpm)(CO)7 complex formally obtained by coupling of the two diynes and a CO molecule on the Ru3 framework. Other products were Ru4(μ4-PhC2C≡CPh)(μ≡dppm)(CO)10 and the already known complex Ru3{μ3-PhCCHCC(C6H4}(μ-dppm)(CO)8. |
| DOI: | 10.1007/BF02498172 |
| Published version: | http://dx.doi.org/10.1007/bf02498172 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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