Adelaide Research & Scholarship
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https://hdl.handle.net/2440/49059
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| Type: | Journal article |
| Title: | An unusual Cu2Ru2 cluster containing a tetrameric phenylethynyl ligand |
| Author: | Bruce, M. Zaitseva, N. Skelton, B. White, A. |
| Citation: | Journal of Organometallic Chemistry, 2008; 693(8-9):1400-1404 |
| Publisher: | Elsevier Science Sa |
| Issue Date: | 2008 |
| ISSN: | 0022-328X |
| Statement of Responsibility: | Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White |
| Abstract: | The reaction between RuCl(PPh3)2Cp* and {Cu(CCPh)}n in refluxing benzene afforded Ru2Cu2(C2Ph)5H2(Cl)(PPh3)Cp*2, which contains an unusual tetramer of the phenylethynyl group which interacts with an Ru…Cu…Cu…Ru chain. The second Ru atom is part of a ruthenocenyl moiety which interacts weakly with the second Cu atom, and bears a vinylidene which bridges an Ru–Cu vector. The structure of a second modification of Ru(Ctriple bond; length of mdashCPh)(CO)(PPh3)Cp* is also reported |
| Keywords: | Copper Ruthenium Cluster Phenylethynyl XRD structure |
| Description: | Copyright © 2007 Elsevier B.V. All rights reserved. |
| DOI: | 10.1016/j.jorganchem.2007.11.002 |
| Published version: | http://dx.doi.org/10.1016/j.jorganchem.2007.11.002 |
| Appears in Collections: | Aurora harvest Chemistry publications |
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