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Type: Journal article
Title: An unusual Cu2Ru2 cluster containing a tetrameric phenylethynyl ligand
Author: Bruce, M.
Zaitseva, N.
Skelton, B.
White, A.
Citation: Journal of Organometallic Chemistry, 2008; 693(8-9):1400-1404
Publisher: Elsevier Science Sa
Issue Date: 2008
ISSN: 0022-328X
Statement of
Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White
Abstract: The reaction between RuCl(PPh3)2Cp* and {Cu(CCPh)}n in refluxing benzene afforded Ru2Cu2(C2Ph)5H2(Cl)(PPh3)Cp*2, which contains an unusual tetramer of the phenylethynyl group which interacts with an Ru…Cu…Cu…Ru chain. The second Ru atom is part of a ruthenocenyl moiety which interacts weakly with the second Cu atom, and bears a vinylidene which bridges an Ru–Cu vector. The structure of a second modification of Ru(Ctriple bond; length of mdashCPh)(CO)(PPh3)Cp* is also reported
Keywords: Copper
XRD structure
Description: Copyright © 2007 Elsevier B.V. All rights reserved.
DOI: 10.1016/j.jorganchem.2007.11.002
Appears in Collections:Aurora harvest
Chemistry publications

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