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https://hdl.handle.net/2440/51873
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Type: | Journal article |
Title: | Some alkynyl-ruthenium complexes containing di-imine and tertiary phosphine ligands |
Author: | Bruce, M. Hall, B. Skelton, B. White, A. |
Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2008; 634(6-7):1097-1101 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2008 |
ISSN: | 0044-2313 1521-3749 |
Statement of Responsibility: | Michael I. Bruce, Benjamin C. Hall, Brian W. Skelton, and Allan H. White |
Abstract: | Reactions between [RuCl2(PPh3)2(Bu 2tbpy)], (1), and terminal alkynes in the presence of Tl[PF6], followed by chromatography on alumina, have given the mono-alkynyl complexes [RuCl(C≡CR)(PPh3)2(Bu 2tbpy)] (R = Ph 2, C6H4NO 2-4 3, CO2Me 4, Fc 5, CPh2(OH) 6), of which the single-crystal XRD molecular structures of 3, 4 and 5 are reported. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. |
Keywords: | Alkynyl Ruthenium Crystal structure Phosphine ligand |
Description: | Article first published online: 5 MAY 2008 |
Rights: | Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/zaac.200800020 |
Appears in Collections: | Aurora harvest Chemistry publications |
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