Adelaide Research & Scholarship
Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/60047
| Citations | ||
| Scopus | Web of Science® | Altmetric |
|---|---|---|
|
?
|
?
|
|
| Type: | Journal article |
| Title: | Formation of an acyl-ethynyl-methylidyne complex of cobalt: structure of Co₃{μ₃-CC(O)C≡C [Ru(dppe)Cp*]} (CO)₈(PPh₃) |
| Other Titles: | Formation of an acyl-ethynyl-methylidyne complex of cobalt: structure of Co(3){mu(3)-CC(O)Ctriple barC [Ru(dppe)Cp*]} (CO)(8)(PPh(3)) |
| Author: | Bruce, M. Zaitseva, N. Skelton, B. White, A. |
| Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2010; 636(6):1075-1077 |
| Publisher: | Wiley-V C H Verlag GMBH |
| Issue Date: | 2010 |
| ISSN: | 0044-2313 1521-3749 |
| Statement of Responsibility: | Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White |
| Abstract: | The reaction between Ru(C≡CH)(dppe)Cp* and Co3(μ3-CBr)(CO)9 in the presence of Pd(PPh3)4/CuI afforded dark red Co3{μ3-CC(O)C≡C[Ru(dppe)Cp*]}(CO)8(PPh3), whose formation may involve attack of the Ru-ethynyl fragment on an intermediate clusterbound CCO ligand; abstraction of PPh3 from the palladium catalyst also occurs. |
| Keywords: | Cobalt Ruthenium Cluster compounds Crystal structure Acyl-ethynyl complex |
| Rights: | Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| DOI: | 10.1002/zaac.200900535 |
| Grant ID: | ARC |
| Published version: | http://dx.doi.org/10.1002/zaac.200900535 |
| Appears in Collections: | Aurora harvest 5 Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.