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Type: Journal article
Title: Syntheses and molecular structures of some polyfluoroaryldiynyl-ruthenium complexes
Author: Bruce, M.
Scoleri, N.
Skelton, B.
White, A.
Citation: Journal of Organometallic Chemistry, 2010; 695(10-11):1561-1568
Publisher: Elsevier Science Sa
Issue Date: 2010
ISSN: 0022-328X
Statement of
Michael I. Bruce, Nancy Scoleri, Brian W. Skelton, Allan H. White
Abstract: Lithiated Ru(C{triple bond, long}CC{triple bond, long}CH)(dppe)Cp* reacts with polyfluoroaromatic compounds C6F5X (X = F, OMe, CN, NO2) and C10F8 to give novel polyfluoroaryldiynyls end-capped with the Ru(dppe)Cp* group. Addition of tcne to Ru(C{triple bond, long}CC{triple bond, long}CC6F5)(dppe)Cp* afforded the butadienynyl Ru{C{triple bond, long}CC[{double bond, long}C(CN)2]C(C6F5){double bond, long}C(CN)2}(dppe)Cp*, while protonation with HBF4·OEt2 resulted in cycloaddition to give [1,3-{Cp*(dppe)RuC{triple bond, long}C}2{μ-C4H(C6F5)2}]BF4. XRD molecular structures of complexes with X = F, CN, OMe and the C10F7 derivative are reported. © 2010 Elsevier B.V. All rights reserved.
Keywords: Alkynyl
Crystal structure
Rights: Copyright © 2010 Elsevier B.V. All rights reserved.
DOI: 10.1016/j.jorganchem.2010.03.017
Grant ID: ARC
Published version:
Appears in Collections:Aurora harvest
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