Adelaide Research & Scholarship
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| Type: | Journal article |
| Title: | Structural studies of several Ru₃ and Ru₄ carbonyl clusters |
| Other Titles: | Structural studies of several Ru(3) and Ru(4) carbonyl clusters |
| Author: | Bruce, M. Humphrey, P. Skelton, B. White, A. |
| Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2011; 637(6):676-681 |
| Publisher: | Wiley-V C H Verlag GMBH |
| Issue Date: | 2011 |
| ISSN: | 0044-2313 1521-3749 |
| Statement of Responsibility: | Michael I. Bruce, Paul A. Humphrey, Brian W. Skelton, and Allan H. White |
| Abstract: | <jats:title>Abstract</jats:title><jats:p>The preparation, characterisation and single‐crystal XRD molecular structure determinations of the three Ru<jats:sub>3</jats:sub> carbonyl clusters attached to carbon ligands, Ru<jats:sub>3</jats:sub>(μ‐H)<jats:sub>3</jats:sub>(μ<jats:sub>3</jats:sub>‐CBr)(CO)<jats:sub>9</jats:sub> (<jats:bold>1</jats:bold>), Ru<jats:sub>3</jats:sub>(μ‐H)(μ‐dppm){μ‐C(OMe)}(CO)<jats:sub>8</jats:sub> (<jats:bold>2</jats:bold>) and AuRu<jats:sub>3</jats:sub>(μ‐H)<jats:sub>2</jats:sub>(μ<jats:sub>3</jats:sub>‐C=C=CHPh)(CO)<jats:sub>10</jats:sub> (<jats:bold>3</jats:bold>) are reported, together with the structures of the tetranuclear hydrido‐carbonyls Ru<jats:sub>4</jats:sub>(μ‐H)<jats:sub>4–2<jats:italic>x</jats:italic></jats:sub>(CO)<jats:sub>11+<jats:italic>x</jats:italic></jats:sub>(PPh<jats:sub>3</jats:sub>) (<jats:italic>x</jats:italic> = 0 <jats:bold>4</jats:bold>, 1 <jats:bold>5</jats:bold>).</jats:p> |
| Keywords: | Ruthenium Cluster compounds Carbon-rich compounds Carbonyl ligands X-ray diffraction |
| Rights: | Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| DOI: | 10.1002/zaac.201000436 |
| Grant ID: | ARC |
| Published version: | http://dx.doi.org/10.1002/zaac.201000436 |
| Appears in Collections: | Aurora harvest 5 Chemistry publications |
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