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Type: Journal article
Title: Syntheses and structural studies of several diynyl-ruthenium complexes and their adducts with cyano-alkenes
Author: Bruce, M.
Burgun, A.
Grelaud, G.
Jevric, M.
Nicholson, B.
Skelton, B.
White, A.
Zaitseva, N.
Citation: Zeitschrift fuer Anorganische und Allgemeine Chemie, 2011; 637(10):1334-1340
Publisher: Wiley-V C H Verlag GMBH
Issue Date: 2011
ISSN: 0044-2313
Statement of
Michael I. Bruce, Alexandre Burgun, Guillaume Grelaud, Martyn Jevric, Brian K. Nicholson, Brian W. Skelton, Allan H. White, and Natasha N. Zaitseva
Abstract: Herein are described some continuing investigations into the reactions of cyano-alkenes with diynyl-ruthenium complexes which have resulted in the preparation and characterisation of diynyl-ruthenium compounds Ru(C≡CC≡CR)(PP)Cp [R = Ph, PP = dppe; R = Fc, PP = dppf; R = CPh=CBr 2, PP = (PPh 3) 2], together with the polycyanobutadienyls Ru{C≡CC[=C(CN) 2]CR=CR′(CN)}(PP) Cp′ [R = Fc, (PP)Cp′ = (dppf)Cp; R = H, SiMe 3, (PP)Cp′ = (dppe)Cp*] formed by [2 + 2]-cycloaddition of the cyano-alkenes to the outer C≡C triple bonds and subsequent ring-opening reactions. Single-crystal XRD molecular structure determinations of six complexes are reported. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords: Ruthenium
X-ray diffraction
Rights: © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
DOI: 10.1002/zaac.201100123
Grant ID: ARC
Appears in Collections:Aurora harvest
Chemistry publications

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