Adelaide Research & Scholarship
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https://hdl.handle.net/2440/74840
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| Type: | Journal article |
| Title: | Reactions of Ru(C≡CPh)(PPh₃)₂Cp with silver(I): molecular structure of [Ag{η²-PhC₂[Ru(PPh₃)₂Cp]}₂]PF₆ and synthesis of a bis(vinylidene) complex |
| Other Titles: | Reactions of Ru(C triple bar CPh)(PPh(3))(2)Cp with silver(I): molecular structure of [Ag{eta(2)-PhC(2)[Ru(PPh(3))(2)Cp]}(2)]PF(6) and synthesis of a bis(vinylidene) complex |
| Author: | Bruce, M. Zaitseva, N. Skelton, B. |
| Citation: | Journal of Organometallic Chemistry, 2012; 716:281-284 |
| Publisher: | Elsevier Science Sa |
| Issue Date: | 2012 |
| ISSN: | 0022-328X 1872-8561 |
| Statement of Responsibility: | Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton |
| Abstract: | Treatment of Ru(CCPh)(PPh3)2Cp 1 with Ag[PF 6] (2/1 molar ratio, in toluene) affords [Ag{η2- PhC2[Ru(PPh3)2Cp]}2]PF6 2, characterised by analysis, spectroscopy and a single-crystal X-ray structure determination. A similar reaction in CH2Cl2 (1/1 molar ratio) gives [{Cp(Ph3P)2Ru}CCHC6H 4CPhC{Ru(PPh3)2Cp}](PF6) 2 4 by oxidative coupling of two alkynyl-Ru radicals. © 2012 Elsevier B.V. All rights reserved. |
| Keywords: | Ruthenium Alkynyl X-ray structure Oxidative coupling |
| Rights: | © 2012 Elsevier B.V. All rights reserved. |
| DOI: | 10.1016/j.jorganchem.2012.05.047 |
| Grant ID: | ARC |
| Appears in Collections: | Aurora harvest Chemistry publications |
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