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|Title:||An investigation of the reaction of dehydrogenating agents with a stable 8-Oxatricyclo[4,3,0,0⁷,⁹]nona-2,4-diene and related Bicylo[4,2,0]octa-2,4-dienes as a potential route to isobenzofurans|
|Other Titles:||An investigation of the reaction of dehydrogenating agents with a stable 8-Oxatricyclo[4,3,0,0(7),(9)]nona-2,4-diene and related Bicylo[4,2,0]octa-2,4-dienes as a potential route to isobenzofurans|
|Citation:||Australian Journal of Chemistry, 1981; 34(4):905-911|
|Richard Y. S. Tan, Richard A. Russell and, Ronald N. Warrener|
|Abstract:||Reaction of the 7,8-dichlorobicyclo[4,2,0]octa-2,4-diene (9) with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone yields the benzocyclobutene (10). Extension of this technique to the related bicyclo[4,2,0]octa-2,4,7-trienes (21) and (23), or 8-oxatricyclo[4,3,0,07,9]nona-2,4-diene (6) was unsuccessful. Manganese dioxide was equally unrewarding while o-chloranil reacted with these olefins to yield benzodioxins in a [4+2] cycloaddition reaction.|
|Rights:||© CSIRO 1981|
|Appears in Collections:||Chemistry publications|
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