Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4482
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| Type: | Journal article |
| Title: | Migration of phenyl from dppm to allenylidene and cyclisation to 1,3-diarylindenyl on an Ru3 cluster |
| Author: | Bruce, M. Skelton, B. White, A. Zaitseva, N. |
| Citation: | Inorganic Chemistry Communications, 1999; 2(1):17-20 |
| Publisher: | Elsevier BV |
| Issue Date: | 1999 |
| ISSN: | 1387-7003 |
| Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
| Abstract: | Thermolysis of Ru3(μ3-C=C=CPh2)(μ-dppm)(μ-CO)(CO)7 affords sequentially Ru3(μ3-PPhCH2PPh3)(μ3-C9H5Ph2)(CO)n (n = 6 (3), 5 (4)) by trapping of the Ph group (from P---C bond cleavage in the dppm ligand) by the allenylidene and cyclisation to a 1,3-diarylindenyl ligand, which is attached to the cluster in 3 via one of the Ar groups and in 4 by the η2:η2:η5-indenyl group; similar experiments with the di-4-tolylallenylidene provide information concerning the course of these reactions. |
| Keywords: | Crystal structures Phenyl migration Ruthenium complexes Allenylidene complexes Carbonyl cluster complexes |
| DOI: | 10.1016/S1387-7003(98)00135-X |
| Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/600912/description#description |
| Published version: | http://dx.doi.org/10.1016/s1387-7003(98)00135-x |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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